| Date | Location | Result | |
| Nov 17, 2012 | Chattanooga, Tenn. | Campbellsville 3, Union University 0 (25-13,25-23,25-14) | Box score |
| Nov 17, 2012 | Chattanooga, Tenn. | Union University 3, Covenant College 2 (25-19,25-21,19-25,16-25,15-13) | Box score |
| Nov 16, 2012 | Chattanooga, Tenn. | Union University 3, Victory University 2 (11-25,25-13,25-23,16-25,15-10) | Box score |
| Nov 16, 2012 | Chattanooga, Tenn. | Campbellsville 3, Union University 1 (25-18,18-25,25-22,25-22) | Box score |
| Nov 16, 2012 | Chattanooga, Tenn. | Union University 3, Victory University 2 (29-31,25-17,25-21,24-26,15-12) | Box score |
| Nov 10, 2012 | Huntsville, Ala. | Alabama-Huntsville 3, Union University 0 (25-17,25-14,25-21) | Box score |
| Nov 09, 2012 | Carrollton, Ga. | West Georgia 3, Union University 0 (25-8,25-20,25-21) | Box score |
| Nov 08, 2012 | Rome, Ga. | Shorter University 3, Union University 0 (25-17,25-15,25-15) | Box score |
| Nov 02, 2012 | Jackson, Tenn. | Arkansas-Monticello 3, Union University 2 (20-25,25-12,24-26,25-21,19-17) | Box score |
| Oct 30, 2012 | Memphis, Tenn. | Christian Brothers 3, Union University 1 (24-26,25-11,25-20,25-15) | Box score |
| Oct 28, 2012 | Valdosta, Ga. | Valdosta State 3, Union University 0 (25-18,25-21,25-20) | Box score |
| Oct 27, 2012 | Pensacola, Fla. | West Florida 3, Union University 0 (25-18,25-20,25-18) | Box score |
| Oct 23, 2012 | Jackson, Tenn. | North Alabama 3, Union University 1 (25-21,23-25,25-22,25-18) | Box score |
| Oct 20, 2012 | New Orleans, La. | Loyola University 3, Union University 0 (25-18,25-20,25-17) | Box score |
| Oct 20, 2012 | New Orleans, La. | University of Mobile 3, Union University 2 (25-27,26-28,25-20,25-18,16-14) | Box score |
| Oct 19, 2012 | New Orleans, La. | Southern University 3, Union University 2 (17-25,27-25,25-22,15-25,16-14) | Box score |
| Oct 19, 2012 | New Orleans, La. | Xavier University 3, Union University 1 (25-18,23-25,25-20,25-17) | Box score |
| Oct 16, 2012 | Nashville, Tenn. | Trevecca Nazarene 3, Union University 0 (25-16,25-19,25-16) | Box score |
| Oct 13, 2012 | Jackson, Tenn. | Union University 3, UWA 2 (25-19,16-25,15-25,25-22,15-11) | Box score |
| Oct 11, 2012 | Searcy, Ark. | Harding 3, Union University 0 (25-17,25-17,25-16) | Box score |
| Oct 05, 2012 | Florence, Ala. | North Alabama 3, Union University 0 (25-13,25-14,25-16) | Box score |
| Oct 02, 2012 | Jackson, Tenn. | Christian Brothers 3, Union University 0 (25-15,25-16,25-20) | Box score |
| Sep 29, 2012 | Jackson, Tenn. | Alabama-Huntsville 3, Union University 1 (21-25,25-23,25-17,25-22) | Box score |
| Sep 28, 2012 | Jackson, Tenn. | West Georgia 3, Union University 0 (25-14,25-16,25-22) | Box score |
| Sep 27, 2012 | Jackson, Tenn. | Shorter University 3, Union University 0 (25-16,25-20,25-14) | Box score |
| Sep 25, 2012 | Jackson, Tenn. | Trevecca Nazarene 3, Union University 1 (28-26,25-20,7-25,25-22) | Box score |
| Sep 23, 2012 | Jackson, Tenn. | Valdosta State 3, Union University 1 (27-25,22-25,25-15,25-15) | Box score |
| Sep 22, 2012 | Jackson, Tenn. | West Florida 3, Union University 0 (25-8,25-10,25-16) | Box score |
| Sep 14, 2012 | Monticello, Ark. | Arkansas-Monticello 3, Union University 1 (26-24,25-19,21-25,25-16) | Box score |
| Sep 14, 2012 | Monticello, Ark. | Union University 3, Miss. Valley St. 0 (25-21,25-22,25-20) | Box score |
| Sep 11, 2012 | Livingston, Al | UWA 3, Union University 0 (25-20,25-16,25-21) | Box score |
| Sep 08, 2012 | Huntsville, Ala. | Union University 3, Albany State 2 (25-20,18-25,16-25,25-21,15-11) | Box score |
| Sep 08, 2012 | Huntsville, Ala. | Florida Tech 3, Union University 0 (25-16,25-15,25-21) | Box score |
| Sep 07, 2012 | Huntsville, Ala. | Union University 3, Paine College 0 (25-7,25-15,25-8) | Box score |
| Sep 07, 2012 | Huntsville, Ala. | Henderson State 3, Union University 1 (25-11,26-24,23-25,25-20) | Box score |